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28 Sep 2012  

Microsoft Community Contributor Award Recipient

Microsoft Windows 10 Pro Insider Preview 64-bit

Welcome aboard, Nick.

A PC will not go to hibernate in some situations like ....

► If there is not enough Space in the C Drive.

Let us see....
Drive    C:
Description    Local Fixed Disk
Compressed    No
File System    NTFS
Size    465.66 GB (500,000,878,592 bytes)
Free Space    34.18 GB (36,698,836,992 bytes)
That's really low. You need to salvage some free space. Try it:
Hard Disk Space - Free Up and Recover

If the Hibernate is disabled. Then it is enable it. Follow the tutorial to enable it:
Hibernate - Enable or Disable

If the hibernate file is damaged.
First disable hibernate. Then run Disk Check, and then enable it again.

Let us know the results.
My System SpecsSystem Spec