Thanks for the welcome.
Did as you said, seems to be stable, will check over the next few days and see what happens. I think what happened, this is someone elses PC, they activated the 30 Day Pro Trial, after switching back to the Free Version, Avast uninstalls some components, therefor the person actually installed MSE, I told them to uninstall one, seeing as the PC started doing this, thinking that the 2 Anti-Virus Programs were creating problem. I'm running MSE now, can probably install Avast again, but think lets not mess with something that is working.
Thanks for the quick response, appreciate it. Will come and Mark as Solved in a few days if the problem doesn't come back. (Doubt it will)