If you are referring to the 100MB System Reserved partition, that isn't unallocated space, it's an NTFS partition that contains the boot manager and other things if Bitlocker is enabled.
use some other software that will
clone the System Reserved partition. Acronis True Image Home 2010 will do it. You can use it on a trial basis to do the cloning:
Complete hard disk recovery solution, backup, drive copy, clone and image computer software
Also, Paragon is well regarded and I'm not sure if the Backup & Recovery 10 Free edition will clone, per se, but some of their other software will, and free trials are available from them, too.
Paragon Software: Download free partition software for home
As for the page file, Windows creates and manages that as a separate file, pagefile.sys. You can modify its size and location under Advanced System Settings.