You can't. You must go to the true "destination". As you saw, Documents and Settings points to \users
Many of us when we first encountered these weird links spent time trying, sometimes with success, to delete them only to find out that we had shot ourselves in the foot since Windows 7 and many apps rely upon those links.
Personally, I wish they had been hidden since they only cause confusion.
But as you noticed,
DIR /AL /S
will show you where they point.