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24 Aug 2010  
Barman58

Windows 8.1 Pro x64 x3 + Windows 10 Preview, Ubuntu
 
 

To answer your question directly the symbolic link will work and is in fact built into win7 under the guise of the location tab on the properties sheet for the user data type folders (documents, pictures, Etc.).

One major issue you may have to deal with ts that you will not have any ACL, (permissions), controls as this is unsupported in Fat32 format drives.

If you leave the system stuff like the Apps filder tree on C: everything should work fine
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