Hello Loyalrogue, welcome to the Seven Forums.
I would start by checking our tutorials. Go here (page "W" on Tutorials
), scroll down the list to find various Windows Live Mail tutorials: http://www.sevenforums.com/1086-post22.html
Next place to check is Windows Live Mail 2011
This video is quite good, I've been referring it to a lot of friends and family members:
Notice it is first of five parts, check out the other four, too.
Hope this gets you started