No, Windows Games Controller won't let you do that, it doesn't work correctly, it doesn't set the individual controller to default and it won't let you recalibrate the existing controller. I could do it originally by changing USB ports but now I've run out of port to try.
I'm going to try one of the WingmanTeam utilities that deletes controller details from the registry.
It's a shame that Microsoft can't produce a more robust piece of software