Thank you Britton30, I suppose if we all the did the obvious first time round these forum pages would be empty!
Your solution worked and my trying within explorer was rubbish, however I have a remaining query/issue:
explorerer still shows 3 users (Admin, my primary account - locked, and Public(?) - locked)
On booting up the primary account, the only account to show on the start up screen, shows as locked although just clicking on it opens the account.
In Control Panel, User Accounts show the primary account and a Guest account (off), is this the same as Public in explorer?
Do I need to unlock these? And if so how do it do it? I never knowingly locked these Users Accounts.
Having deleted the temporary xfer account I find I still cannot delete the now defunct C drive primary account folder & files, but I guess as greg suggested, I should just ignore them?
Hopefully all goes to the E drive & nothing will get directed to them in the future.
Thank you both for the assistance, since this is likely to be a more & more common need by users of SSDs hopefully the future might bring a more user friendly method for the layman? Some form of drag and drop would be brilliant!