I assume you have Catalyst Control Center installed? If you do, start it; click the GRAPHICS tab at the top left; select DESKTOP DISPLAYS in the drop down menu; click the black triangle of the display you want to change the properties of; click PROPERTIES in the drop down menu; select the resolution for your display; click apply, then OK.
In Windows: Right click on an open spot on your desktop; select SCREEN RESOLUTION; select the screen in question and choose resolution.