I think that the Chieftec may be a little weak. I see that it's rated at 14 and 15A on its two +12V rails.
ATI certifies PSUs:
ATI CrossFireX™ | GAME.AMD.COM
(It's a Crossfire site, but it covers single cards as well.) The lowest power supply certified for a single HD4890 is a 500W Zalman unit with two 18A +12V rails.
Your Chieftec unit wouldn't be on the list, even if it was adequate, because it has a single PCI-E connector. (You need two 6 pin ones. You might be able to get away with the molex-to-PCI-E adapter that most cards include.)
If you want CrossfireX, at current prices, I'd suggest two 4870s in SLI rather than 4850s. However, you'd need *four* PCI-E connectors. This one would work:
Newegg.com - PC Power & Cooling S75CF 750W EPS12V SLI Certified CrossFire Ready 80 PLUS Certified Active PFC Power Supply - Power Supplies
(PC Power & Cooling Silencer 750 Crossfire, in ATI Red.) I've run a pair of 4870s with one. (It's rated at 60A on its *single* +12V rail.)