Once you start moving things about like that it complicates matters very considerably, especially if you need to change something later. For the vast majority of users the system default settings are more than adequate, and unless you have a special reason for changing them it is better not to do so.
Having said that, I don't think you can do much with that configuration in its present state. You appear to have essential system files on both partitions. If you simply remove the system files from D: your system will no longer work.
You could try moving them back to the way they were. See also;
User Folders - Change Default Location - Windows 7 Forums
But what I would do in a situation like that is to reinstall windows and set it up properly. If you have good backups of your data that should not be a problem. Your system will then be fresh, and you wont waste a great deal of time and effort on something quite involved and complex which also might not work.
Regards....Mike Connor