Yes. Tried formatting the rogue stick on the XP machine and it behaves (to me) normally - XP m/c sees it straight away, can format it, can transfer files to it, etc.
The sister stick is FAT and can be seen on both machines.
Putting the offending disk, reformatted FAT, in Windows 7 machine and its still not visible in explorer, but is in disk management, but cannot be allocated a drive letter.
Only difference I can see between the sticks (looking on the XP machine) is the 512 byte allocated on the sister stick.