Hmmm, this is not my forte but, have you tried to use only the 4GB stick on the Primary slot (I think its the closest to the cpu) to test if it works on its own? if it does, then shut down the rig and insert the 2GB on the secondary slot and test it again... that may do the trick.
If it freezes again, then it is easy to see that there is a conflict with both sticks and/or your Mobo has the capability for more than 4GBs?