This is what I do. User Folders - Change Default Location
I move the user files, make sure the SSD is aligned, make sure Windows turned off Defrag, disable hibernate and not much more.
To disable Hibernate, in an elevated command prompt, type powercfg -h off
and press enter. It will look like it did nothing but it did.
To make sure trim is enabled in the elevated command prompt type (copy/paste) fsutil behavior query disabledeletenotify
and press enter if it returns DisableDeleteNotify = 0 then trim is enabled.