Hello Bigmck I am no expert as you know but copying the docs over would be fairly simple I would have thought.
Now I have tried setting labels using the Partition Wizard and well it might be just the way I am doing it but it does not let me label the second drive with drive letter already in use by another drive.
I guess you could try putting those docs onto a stick remove the HDD then label the SSD partition E: and paste in the docs into that E: partition from the stick?
I am probably being too over simplistic and someone will come up with a system that will make mine look Neanderthal but that is what I would be trying.