as Dwarf said, DVD-R are only writable ONCE, if you wanted to erase and write other stuff, you must purchase DVD RW (rewritable).
Since you are using a DVD anyway, I'd suggest to make a Windows 7 installation disk, which can do all system repair functions AND also install a new Windows 7 in case you need it.
This tutorial provides links to clean Windows 7 iso files (basically a digital Windows 7 disk ready to be burned on a DVD with any serious disk burning tool), and how to place that on a thumbdrive if you want to use that instead (as it has way faster load times when you are using it).