I hope that you had connected both the power cables and SATA cables to your drives and checked that are plugged securely.
That apart, if your computer is quite old it most likely caters to only 1,5GB/sec SATA drives - in other words your motherboard may only have 1.5GB SATA Controllers. If you are connecting 3GB SATA drives, you may have to jumper it to 1.5 GB for these to be recognised. Just check on this.