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You can add any folder to a library or create a new library, but this does not move any files. The library only gathers links. In other words, if a program you installed wanted to create a folder in 'Documents' the folder would still be on the C: drive as you have not moved the original Document folder.
The first link I gave you will show you how to actually move that documents/music/pictures folder to the E: drive. If you make the E: drive your documents folder using this method, then when something of that nature happens, the folder will be created on the E: drive.
Maybe you already know all that, but I just want to be sure.
Gary
I just reinstalled windows and tested out the registry edit to change where the user folder is located and it worked perfectly :) just run cmd when your about to enter in the user profile info during install and voila
Windows 7 Move the Users and Program Files Directories To A Different Partition | Tuts4Tech