mjames53ip, welcome to the forums.
What happened is that the boot record/MBR for the 32 bit install was on the XP drive and installing the 64 bit on it overwrote it, that is why you don't have the boot menu or why the 32 bit install won't boot.
You should be able to fix it by booting from the 32 bit disk and running the Startup Repair,
Startup Repair
Also if you want to make it so that you use the bios to decide which to boot from instead of the Windows bootloader, disconnect the 64 bit drive beforehand then reconnect once the 32 bit install is working again.