If you created table of contents through
References - Table of Contents, you can hold Ctrl and click on the item in that table, word will take you there. This feature is standard.
Also, to navigate inside document you can use bookmark option.
Insert bookmarks.
Word 2010 Bookmarks
Then insert Hyperlink - in the window select second tab "Place in This Document" and choose your bookmark.
As for hiding parts of document, I do not think that is possible.
You can create that in HTML document with javascript, but not in Word document.