Windows 7 - Backing up Mail and Settings... Outlook 2010

I am trying to migrate all my settings and emails (Outlook 2010)from One computer to another but I am having difficulty accomplishing my task

One PC is running Windows XP 32 bit and I am trying to migrate my settings to the new one running Windows 7 64 bit, which should not be a problem, right? I would not ask for help if it was only 1 email account but I am running 3 email account from Outlook and I can't remember the settings of 2 of them as it is... it has been a while

Office 2010 backup method suck from here to the Moon since you may be able to export your Data but NOT the settings.

1st thing I tried was Backrex Demo, it did its job on the XP side of things but on the Win 7 side it tells me that it does not find my outlook even though it is installed. Heck, I even installed the one I do remember but to no avail... Backrex told there was no Outlook installed.

Granted, it was only a Demo and I sure the heck don't want to spend money for the Paid version if it will not do what its supposed to.

So, any FREE third party Apps I can run or heck, I would be glad if Microsoft can throw us a bone and give us something to work with.

Not sure if this will help, but I'll post it anyway.

Windows Live Mail, Messenger, Contacts, And Calendar Backup

It seems there are quite a few programs on the market, but of course they want some of your lovely dollars.

Admins/Mods, sorry for the double post but I was able to find that other post by going to google and searching but was unable to find it when I searched here.

You can delete this one if you want... I will leave that other link here

How to save & move Outlook settings, etc.?