Hiya and welcome to the forums
One quick way to do it is to Go to Internet Options in the Control Panel (on the PC you want to block). Go to the Connections tab and click LAN settings. Uncheck "Automatically detect settings" and then check "Use proxy server" and put settings in for a proxy server that doesn't exist. This will time out the Web browser each time a user tries to pull up an Internet site.
Another way is to put in the correct ip address manually but set the gateway/dns incorrectly.
Alternatively, you can set the Internet router to deny all port 80 traffic to the WAN from the IP address of the client PC you want to block. But this is a bit more involved.