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To change your computers DNS you would click Use the Following DNS Server Addresses.
In Preferred DNS Server put : 8.8.4.4
In Alternate DNS Server put: 8.8.8.8
Should look something like this:
Let us know how you get on,
Can you give a short explanation why. I thought the router DNS setting would be used as its what is used to connect to the Internet.
Yes but at the minute your computer looks at the router for a DNS to use. However changing that tells your computer not to look at the router for a DNS.
If you are looking at blocking people using a different DNS you may be able to block this on your router.