Hybrid mode is to have the computer go to sleep first, then after the time you set will go into hibernation. That is why it is taking a bit longer since your computer is resuming from hibernation and not sleep.
For you what you want, you would need to set your Power Plan settings to "Sleep" and turn off "Hybrid" and "Hibernate" like in the recommended "Sleep" settings in the tutorial below. Afterwards, the computer should wake up from sleep and be ready to go in a second or two. Power Plan Settings - Change
Hope this helps,