First off, I agree with zigzag 3143, to wit: 6% is nothing to be concerned about. But that's we not thee.
Windows does, indeed, "lock" some files to which, normally, a defrag will be denied access. I use a free, I think excellent, open source app called UltraDefrag which has the ability to defrag most locked files. You will fine it at
SourceForge
Monk