User Account Control setting

Is there any additional security protection to be gained by moving the UAC slider from the default setting to its highest setting on the administrator account (to notify when changing Windows settings?)

I use a standard user account for most of my work, so this setting will only take effect when the elevation prompt appears. I generally know when I am changing a Windows setting, don't need to be notified, but I'm wondering if this setting will block some actions by malware.

Thanks

Thanks for the replies.
I did some digging and found this on a page from MS: (refers to the default setting for the admin account)

Notify me only when programs try to make changes to my computer
•You'll be notified before programs make changes to your computer that require administrator permissions.
•You won't be notified if you try to make changes to Windows settings that require administrator permissions.
•You'll be notified if a program outside of Windows tries to make changes to a Windows setting.

•It's usually safe to allow changes to be made to Windows settings without you being notified. However, certain programs that come with Windows can have commands or data passed to them, and malicious software can take advantage of this by using these programs to install files or change settings on your computer. You should always be careful about which programs you allow to run on your computer.

The underlines are mine. It seems like this is the point that one must decide upon. If malware is able to make windows think that you are the one making the change to a Windows program, then you are not protected.

What you state is actually true of two other settings. It applies to the default setting, which is the second highest, and the setting below that one.

Read it here:
What are User Account Control settings?