Brink - I think we are miscommunicating with each other. Either that, or I am being an idiot.
Let me walk through my issue with steps for you to follow (if you have time):
1) Open C:/users/_______/My Pictures.
2) Do you already have some folders in there? If not, create a new folder in My Pictures named XYZ.
3) Open XYZ and place a picture in that folder.
4) Change the view for XYZ to "large icons."
5) Go back one directory to "My Pictures." Change the view to "list."
Now, as you will see, any time you go into C:/users/_____/My Pictures, the initial view will be "list" view. However, every time you go into XYZ, the pictures are shown in "large icons." There is a happy combination of both "list" and "large icon" views. List makes sense for the folders, and large icons makes sense for the pictures.
Now, the problem. This does not work for the "Pictures" library. I've tried everything. But, it seems that every single folder in the "Pictures" library and every picture contained in those folders shows up in one uniform folder view (either "list" or "large icons," but never a combination of the two like C:/users/______/My Pictures).
Does that make sense?