Ok I don't know what video that was but the black is always to black as you found.
That green lead is a pic that can be sorted to a black pin because that is the power on switch connections?
Now wanting you to play around with any pSU's unless you are fairly savvy with them because there are parts - usually the large capacitors in them that hold a high voltage charge very similar to a heart defibrillator and yes it will have the same effect on you as one.
In nutshell defibs are used to actually stop all electrical activity in the heart in the hope that it will start beating in a normal rhythm because a lot of heart attacks are caused when the heart starts to beat in a rhythm that is not conducive to life. . I know this because I am an RN of 44+ years so please DO not mess with these devices unless you know what you are doing.
I do have an old PSU set up to test fans etc using a bridge connection between the black and green pins but again
unless you research it really well DO NOT try to use one for anything without the knowledge needed.
NOw backing up - the blue lead is actually the -12v (negative) pin and it's importance is not really that relevant these days - I stand to be corrected of course.
The colours that are important are yellow +12v (positive) red +5v and orange +3.3v
Now those readings have to be with +/- 5% of the required voltage any more or less can cause damage to components though most modern PSU's have circuitry (POWER_GOOD +5v grey cable pin) that will not allow a machine to boot or even start for that matter if the +5 does not appear at the grey pin when powering up the machine.
See this table
Limits +/- (minimum - correct - maximum)
12v1 = 11.4 - 12 - 12.6v
12v2 = 11.4 - 12- 12.6v
5v = 4.75 – 5 - 5.25v
3.3v = 3.135 – 3 – 3.465v
-12v = -10.80 - -12 - -13.20v
+5VSB = 4.75 – 5 - 5.25v
The Power good signal voltage at pin 8 on the 24 pin plug (grey cable) should be the same as the 5v rail reading/s
But well done for getting that done as it is in my mind better than getting reading from softwares that can be often off mark personally I don't really rely too much on the BIOS but others may disagree.