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#11
For the third time: Storage Boot Option Control may need to be Enabled to boot a flash stick. It may even pertain to disk. I would have it enabled for Legacy or both.
Read the manual for your BIOS on the mobo's Support Downloads webpage to see what those Secure boot states are needed for and if they apply for you. Study fully the other settings to familiarize yourself with them.
Boot override choices are most often if you want to temporarily boot from media or another choice than the Boot Priority order, and should be the same as the BIOS Boot menu key choices which every mobo has, but isn't accessible in Windows 8 except via the Advanced Boot options.