I just had a cursory glance at your motherboard manual.
In the BIOS you should have enabled
Machine Mac (NV) Address Input to be able to enter the
MAC(NV) Address Input. Simply by disabling it and saving the setting should take away the address you entered. That is what my common sense tells me

. What is that address you entered? Some Random Number?
In the same page enable the Marvel LAN. Again do not forget to save the settings.
Provided you had installed the drivers correctly for both the LAN and the
LAN hardware is functional, Windows will always get the hard encoded Mac numbers for both the LAN.
To check open command prompt ( Start > All Programs > Accessories > Command prompt ) and type getmac /v and press enter.
You should see the MAC address of both your LAN.
If you still have problems, its beyond me

. Let other experts deal with it.( I would return the board and get a new one.)