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#20
Hello @bawldiggle, :)
This tutorial will only allow or prevent user from being able to "Unblock" a file. It won't help for what you want.
Instead, you could create an elevated shortcut of the "ShiftOff.exe" file using the tutorial below, and place the elevated shortcut in your Startup folder to be able to run it elevated at startup.
Elevated Program Shortcut without UAC Prompt - Create - Windows 7 Help Forums