Increased RAM causes Win 7 to hang on boot

The possibility of it being BIOS related had occurred to me fairly early in the proceedings, but my board was making the update difficult, so I tried many other things first.
 

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At a glance

Windows 7 Ultimate 64 bitAMD Athlon 64 5600+2 GBATI 8500
OS
Windows 7 Ultimate 64 bit
CPU
AMD Athlon 64 5600+
Motherboard
Asus M2-AVM
Memory
2 GB
Graphics Card(s)
ATI 8500
Monitor(s) Displays
AOC 22" LCD flat panel
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