Wireless or wired network? You're going to want to employ some sort of ACL or blacklist by logging into either a router and / or switch depending on your network topology. You'll have to identify the hosts that you don't want on your network and blacklist their MAC addresses. So if you have Alice-PC on the network and you don't want her there, open command prompt and ping Alice-PC to get her IP. When that comes back, match that PCs IP to its MAC address by looking at your ARP table (do an "arp -a" from the command prompt). This is a simple scenario as to how you could go about doing this, yours may vary.