On a legacy-MBR disk, BIOS take the boot process to a MBR on a disk that takes to a a partition that has a Boot Loader and is marked as active.
- Most OEM computers has a System partition (not M$ reserved) that has the boot loader and is marked as active. This partition has some OEM programs (like maintenance and Factory recover).
- If you have installed Win 7 on a disk, the boot loader is on C: drive / partition and is marked as active.
As you have two Win installations, only one will be marked as active (last installed).
If you want to dual boot, you have to modify the boot loader to add the second option.
Use easyBCD
EasyBCD - NeoSmart Technologies (non comercial - Register - Download)